Abstrakt

In situ hydrothermal synthesis ofCo(III) formats coordination polymer

Jian-Long Du

One newCo(III) complex {[CoL3]3(CH3OH)3}8 [HL= format]was prepared by hydrothermal reaction and structurally characterized. Single crystal Xray diffraction analysis revealed that the Co(III) is six-coordinate by six oxygen atoms of six L ligand. Crystal data: triclinic, space group R-3c, a =8.2379(12)Å, b=8.2379(12)Å, c=22.353(5)Å,=90°,  =90°, = 120°, V = 1313.7(4)Å3, Z= 2,D= 1.684Mg·m-3.