Abstrakt

Electrochemical Reduction of Zn (II) l-Amino Acids System in Aqueous Formamide Mixture at D. M. E.

B. S. Bairwa, Hemlata Agarwal, I. K. Sharma, Sarita Varshney and P. S. Verma

Kinetic parameters of Zn (II) in presence of ligand l-lysine, l-aspartic acid, l-glutamic acid, larginine, l-tryptophan and l-tyrosine at pH 7.50 ± 0.02 and at constant ionic strength μ = 0.1 NaClO4 have been evaluated. The reductions in all these cases were found to be quasi reversible and diffusion controlled. The values of kinetic parameters for the electrode processes viz ,  and ks have been evaluated using Gelling’s treatment1 and Er 1/2 values were also calculated for quasi reversible electrode processes.