Abstrakt

A zinc(II) complex chelated by 1,10-phenanthroline ligand: Synthesis, crystal structure and hirshfeld surface analysis

Xuemei Li, QingmingWang, JianhongXi, Hong Zhai, Sisi Feng, Miaoli Zhu

In this paper, the synthesis, crystal structure, BVScalculation and hirshfeld surfaces and fingerprint plots analyses of a new complex [Zn(phen)2(H2O)Cl]Cl (phen = 1,10-phenanthroline) are reported.TheX-ray structure analysis of the complex revealed the zinc ionwas located in the six-coordinated octahedral geometry, consisted of fourNatoms, onewatermolecules and aCl atom. BVS calculation associatedwith crystal structure confirmed the +2 oxidation state of themetal cations.Hirshfeld surfaces and fingerprint plots analyses indicated that besidesO- H···Cl there were also C-H···Cl, C-H···O and ð···ðweak interactions in the complex,which linked molecules forming 1Dwavychains, then 2Dlayer and 3Dnet structure.